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feel free to Contact Us.1. Field of the Invention
This invention is directed toward the preparation of a non-degradable polymeric fiber and, more particularly, to a method of producing a fiber which swells in water and is highly resistant to chemical attack.
2. Description of the Prior Art
Rigid, non-degradable polymeric fibers used for filtering air must retain their filtering capability while resisting attack by water-soluble fluids and chemical agents. For this reason, filtering materials must be essentially non-swellable or resist swelling in the presence of water. In some cases, it is desirable to use the filtering material in the filtration of highly concentrated materials, such as nuclear waste products and the like. In such cases, the fibers used must be chemically resistant to solvents and salt solutions. In addition, while a filtering material must be sufficiently strong to withstand the mechanical treatment to which it is subject during use and fabrication, it must be sufficiently porous to provide adequate surface area for filtration.
Acrylic based fibers used in filtration applications have the required mechanical strength, dimensional stability and durability, and they are suitable for use in nuclear and conventional waste products. Acrylic-based fibers, however, are not resistant to most chemicals and they are readily soluble in water. In addition, acrylic based fibers will swell in the presence of water to the point that the filtration material loses its filtering capability. Attempts to chemically modify the fiber such as copolymerization, cross-linking, grafting, or reaction of the acrylic monomer and additives with the fiber have met with only partial success.
An alternative to acrylic-based fibers is polyvinylidene fluoride (PVDF). PVDF is a semicrystalline polymer which is insoluble in organic solvents and stable at temperatures above 400.degree. F. It has been found, however, that PVDF-based fibers swell and lose their ability to filter gases and water-soluble substances when contacted with water. As a result of this undesirable property, PVDF fibers have not been widely used in filtering applications.
A further disadvantage of PVDF fibers is that they have poor tensile strength. Thus, PVDF fibers are not readily incorporated into reinforcing filaments, and
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Tofu production in Brazil, 2011: evolution and prospects for the future.
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